The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Alkanes+alkyl radicals / Alkanes / CH4 / SPARC(2013)_298K_121.567nm(rec)

DATAFILE: CH4_SPARC(2013)_298K_121.567nm(rec).txt
NAME: methane
FORMULA: CH4
AUTHOR(YEAR): SPARC(2013)
T: 298K
λ: 121.567nm(rec)
BIBLIOGRAPHY: J.B. Burkholder, W. Mellouki, E.L. Fleming, C. George, D.E. Heard, C.H. Jackman, M.J. Kurylo, V.L. Orkin, W.H. Swartz, and T.J. Wallington, "Evaluation of Atmospheric Loss Processes: Photochemistry Supplement", SPARC Lifetimes Report (2013) – SPARC Report No. 6, Chapter 3: Supplement 4, 3S4-1 - 3S4-52 (2013); www.sparc-climate.org/publications/sparc-reports/
COMMENTS: Recommended absorption cross section at the Lyman-α wavelength with an estimated uncertainty factor p(298 K) = 1.3

The value is based on the results (which are are in reasonable agreement at 121.567 nm) of

K. Watanabe, M. Zelikoff, and E.C.I. Inn, "Absorption coefficients of several atmospheric gases", Air Force Cambridge Research Center Technical Report, 53-23 (1953),

R.W. Ditchburn, "Absorption cross-sections in the vacuum ultra-violet. III. Methane", Proc. Roy. Soc. London A 229, 44-62 (1955): DOI: 10.1098/rspa.1955.0073,

H. Sun, and G.L. Weissler, "Absorption cross sections of methane and ammonia in the vacuum ultraviolet", J. Chem. Phys. 23, 1160-1164 (1955); DOI: 10.1063/1.1742205,

A.H. Laufer and J.R. McNesby," Deuterium isotope effect in vacuum-ultraviolet absorption coefficients of water and methanes", Can. J. Chem. 43, 3487-3490 (1965); DOI: 10.1139/v65-495,

C. Backx, G.R. Wight, R.R. Tol, and M.J. Van der Wiel, "Electron-electron coincidence measurements of CH4", J. Phys. B: At. Mol. Phys. 8, 3007-3019 (1975); DOI: 10.1088/0022-3700/8/18/020,

G.H. Mount, E.S. Warden, and H.W. Moos, "Photoabsorption cross sections of methane from 1400 to 1850 Å", Astrophys. J. 214, L47-L49 (1977); DOI: 10.1086/182440,

L.C Lee and C.C. Chiang, "Fluorescence yield from photodissociation of CH4 at 1060-1420 Å", J. Chem. Phys. 78, 688-691 (1983); DOI: 10.1063/1.444812,

A.Y.T. Lee, Y.L. Yung, B.M. Cheng, M. Bahou, C.-Y. Chung, and Y.P. Lee, "Enhancement of deuterated ethane on Jupiter", Astrophys. J. 551, L93-L96 (2001); DOI: 10.1086/319827,

J.W. Au, G. Cooper, G.R. Burton, T.N. Olney, and C.E. Brion, "The valence shell photoabsorption of the linear alkanes, CnH2n+2 (n=1-8): Absolute oscillator strengths (7-220 eV)", Chem. Phys. 173, 209-239 (199310.1016/0301-0104(93)80142-V); DOI: ,

R.A. Brownsword, M. Hillenkamp, T. Laurent, R.K. Vatsa, H.-R. Volpp, and J. Wolfrum, "Quantum yield for H atom formation in the methane dissociation after photoexcitation at the Lyman-α (121.6 nm) wavelength", Chem. Phys. Lett. 266, 259-266 (1997); DOI: 10.1016/S0009-2614(96)01526-6,

R.K. Vatsa and H.-R. Volpp, "Absorption cross sections for some atmospherically important molecules at the H atom Lyman-α wavelength (121.567 nm)", Chem. Phys. Lett. 340, 289-295 (2001); DOI: 10.1016/S0009-2614(01)00373-6,

K. Kameta, N. Kouchi, M. Ukai, and Y. Hatano, "Photoabsorption, photoionization, and neutral-dissociation cross sections of simple hydrocarbons in the vacuum ultraviolet range", J. Electron Spectrosc. Related Phenom. 123, 225-238 (2002); DOI: 10.1016/S0368-2048(02)00022-1, and

F.Z. Chen and C.Y.R. Wu, "Temperature-dependent photoabsorption cross sections in the VUV-UV region. I. Methane and ethane", J. Quant. Spectrosc. Radiat. Transfer 85, 195-209 (2004); DOI: 10.1016/S0022-4073(03)00225-5

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